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The atmosphere is a unit of pressure approximately equal to the average atmospheric pressure at sea level on Earth, which is about 101,325 Pascals or 101.325 kilopascals. It's often used in weather reports and discussions of atmospheric pressure.
The megapascal is equal to 1,000,000 Pascals or one million Pascals. It's commonly used in engineering and materials science, particularly in discussions of material strength.